8.8÷1.1+3.9÷1.3 12.56x0.8-9.75÷3 43.5x2.9的积是（）位小数,0.125x8是（）位小数 5.6x0.5表示（）6x0.5表示（）7.2与4.8的差乘以3.5,所得的积是_百度作业帮
8.8÷1.1+3.9÷1.3 12.56x0.8-9.75÷3 43.5x2.9的积是（）位小数,0.125x8是（）位小数 5.6x0.5表示（）6x0.5表示（）7.2与4.8的差乘以3.5,所得的积是
8.8÷1.1+3.9÷1.3 12.56x0.8-9.75÷3 43.5x2.9的积是（）位小数,0.125x8是（）位小数 5.6x0.5表示（）6x0.5表示（）7.2与4.8的差乘以3.5,所得的积是
8.8÷1.1+3.9÷1.3 =8+3=1112.56x0.8-9.75÷3 =12.5×0.8+0.06×0.8-3.25=10+0.048-3.25=6.79843.5x2.9的积是（2）位小数,0.125x8是（0）位小数 5.6x0.5表示（5.6的10分之5是多少） 6x0.5表示（6的10分之5是多少）7.2与4.8的差乘以3.5,所得的积是8.4 （7.2-4.8）×3.5=2.4×3.5=8.4
16.984减去24.8与12.5的商，再加上12.65，和是多少？
一个梯形花坛种花3750株，这快地两底分别长15米和10米，高是12米。每株花占地多少平方米？
一堆相同的圆形木料，上层堆放12根，最下层是24根，每相邻两层相差一根，这堆圆形木料共有多少层？
三角形的面积与平行四边形的面积相等，底也相等。平行四边形的高是4厘米，三角形的高是（）厘米。
16.984减去24.8与12.5的商，再加上12.65，和是多少？
16.984-24.8÷12.5+12.65
=16.984-1.984+12.65
一个梯形花坛种花3750株，这快地两底分别长15米和10米，高是12米。每株花占地多少平方米？
（15+10）×12÷2÷3750
=150÷3750
=0.04平方米
一堆相同的圆形木料，上层堆放12根，最下层是24根，每相邻两层相差一根，这堆圆形木料共有多少层？
24-12+1=13层
(12+24)×13÷2
=36×13÷2
三角形的面积与平行四边形的面积相等，底也相等。平行四边形的高是4厘米，三角形的高是（8）厘米。
两个问题啊9.8x65.2x1.25-12.5x0.62x18怎么简算_百度知道
9.8x65.2x1.25-12.5x0.62x18怎么简算
我有更好的答案
9.8x65.2x1.25-12.5x0.62x18=98x65.2x0.125-0.125x62x18=0.125x(98x65.2-62x18)=0.125x(98x62+98x3.2-62x18)=0.125x[(98-18)x62+98x3.2]=0.125x80x62+0.125x8x98x0.4=620+(100-2)x0.4=620+40-0.8=659.2
你好！够了吧！ 1.125*3+125*5+25*3+25 2.*11*(101-92) 3.(23/4-3/4)*(3*6+2) 4. 3/7 × 49/9 - 4/3 5. 8/9 × 15/36 + 1/27 6. 12× 5/6 – 2/9 ×3 7. 8× 5/4 + 1/4 8. 6÷ 3/8 – 3/8 ÷6 9. 4/7 × 5/9 + 3/7 × 5/9 10. 5/2 -（ 3/2 + 4/5 ） 11. 7/8 + （ 1/8 + 1/9 ） 12. 9 × 5/6 + 5/6 13. 3/4 × 8/9 - 1/3 14. 7 × 5/49 + 3/14 15. 6 ×（ 1/2 + 2/3 ） 16. 8 × 4/5 + 8 × 11/5 17. 31 × 5/6 – 5/6 18. 9/7 - （ 2/7 – 10/21 ） 19. 5/9 × 18 – 14 × 2/7 20. 4/5 × 25/16 + 2/3 × 3/4 21. 14 × 8/7 – 5/6 × 12/15 22. 17/32 – 3/4 × 9/24 23. 3 × 2/9 + 1/3 24. 5/7 × 3/25 + 3/7 25. 3/14 ×× 2/3 + 1/6 26. 1/5 × 2/3 + 5/6 27. 9/22 + 1/11 ÷ 1/2 28. 5/3 × 1...
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出门在外也不愁Document Detail
(Nitrato-κO)tris-[tris-(4-fluoro-phen-yl)phosphane-κP]copper(I).
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PubMed-not-MEDLINE
Abstract/OtherAbstract:
In the title complex, [Cu(NO(3))(C(18)H(12)F(3)P)(3)], the ligating atoms define a distorted tetrahedon with the three tris-(4-fluoro-phen-yl)phosphane ligands in the basal positions and the nitrate ligand in the axial position. The intra-molecular π-π inter-action [centroid-centroid distance = 3.6113 (11) ?] between two of the 4-fluoro-phenyl groups is complemented by both C-H?F and C-H?O inter-actions with distances in the range 2.51-2.60 ?, resulting in a tight head-to-tail packing.
Tania N H Andreas Roodt
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Acta crystallographica. Section E, Structure reports online
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Acta Crystallogr Sect E Struct Rep Online
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Department of Chemistry, University of the Free State, PO Box 339, Bloemfontein 9300,
South Africa.
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From MEDLINE(R)/PubMed(R), a database of the U.S. National Library of Medicine
Journal Information
Journal ID (nlm-ta): Acta Crystallogr Sect E Struct Rep Online
Journal ID (iso-abbrev): Acta Crystallogr Sect E Struct Rep Online
Journal ID (publisher-id): Acta Cryst. E
Publisher: International Union of Crystallography
Article Information
A full version of this article is available from Crystallography Journals Online.(C) Hill and Roodt 2012
open-access:
Received Day: 27 Month: 9 Year: 2012
Accepted Day: 18 Month: 10 Year: 2012
collection publication date: Day: 01 Month: 11 Year: 2012
Electronic publication date: Day: 24 Month: 10 Year: 2012
pmc-release publication date: Day: 24 Month: 10 Year: 2012
Volume: 68 Issue: Pt 11
First Page: m1396 Last Page: m1397
PubMed Id:
ID: 3515141
Publisher Id: mw2090
Coden: ACSEBH
Publisher Item Identifier: S3346
(Nitrato-κO)tris-[tris-(4-fluoro-phen-yl)phosphane-κP]copper(I)
Alternate Title:[Cu(NO3)(C18H12F3P)3]
Tania N. Hill*
Andreas Roodt
aDepartment of Chemistry, University of the Free State, PO Box 339, Bloemfontein 9300, South Africa
Correspondence: Correspondence e-mail: tania.
Related literature
For related complexes, see: Hanna et al. (2005); Steyl (2009); Saravanabharathi et al. (2002); Dyason et al. (1986); Matthew et al. (1971). [Chemical Structure ID: scheme1]
Experimental
Crystal data
[Cu(NO3)(C18H12F3P)3]
Mr = 1074.29
Triclinic,
a = 9.3861 (3) ?
b = 12.2552 (4) ?
c = 21.4820 (7) ?
α = 85.274 (2)°
β = 86.843 (1)°
γ = 74.954 (1)°
Mo Kα radiation
μ = 0.64 mm-1
0.38 × 0.11 × 0.08 mm
Data collection
Bruker X8 APEXII 4K KappaCCD diffractometer
Absorption correction: multi-scan (SADABS; Bruker, 2004) Tmin = 0.792, Tmax = 0.950
28458 measured reflections
11760 independent reflections
9439 reflections with I & 2σ(I)
Rint = 0.030
Refinement
R[F2 & 2σ(F2)] = 0.035
wR(F2) = 0.085
11760 reflections
640 parameters
H-atom parameters constrained
Δρmax = 0.40 e ?-3
Δρmin = -0.41 e ?-3
Data collection: APEX2 (Bruker, 2005); cell refinement: SAINT-Plus (Bruker, 2004); data reduction: SAINT-Plus and XPREP (Bruker, 2004); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: DIAMOND (Brandenburg & Putz, 2005); software used to prepare material for publication: WinGX (Farrugia, 1999).
Supplementary Material
Crystal structure: contains datablock(s) global, I. DOI: 10./mw2090sup1.cif
Structure factors: contains datablock(s) I. DOI: 10./mw2090Isup2.hkl
Additional supplementary materials:
crystall 3D checkCIF report
fnu1Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: MW2090).
Financial assistance from the University of the Free State is gratefully acknowledged. We also express our gratitude towards SASOL and the South African National Research Foundation (SA-NRF/THRIP) for financial support of this project. Part of this material is based on work supported by the SA-NRF/THRIP under grant No. GUN 2068915. Opinions, findings, conclusions or recommendations expressed in this material are those of the authors and do not necessarily reflect the views of the SA-NRF.
supplementary crystallographic
information
Experimental
tris-4-fluorophenylphosphane (2 mmol) was added to a solution of CuNO3
(1 mmol) in warm MeOH (15 ml, 70 °C) and the resulting solution was stirred
for c.a. 1 h. The solution was filtered and allowed to cool slowly.
Crystals suitable for single-crystal X-ray diffraction were obtained from the
slow evaporation of the solution.
Refinement
All H atoms were placed in geometrically idealized positions and constrained to
ride on their parent atoms, with C—H = 0.95 ? and Uiso(H) = 1.2
Ueq(C) for aromatic H atoms.
Crystal data
Data collection
Refinement
Special details
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (?2)
Atomic displacement parameters (?2)
Geometric parameters (?, ?)
Hydrogen-bond geometry (?, ?)
Symmetry codes: (i) x-1, y+1, z; (ii) x-1, y, z; (iii) -x+1, -y+1, -z+1; (iv) x, y-1, z; (v) -x+1, -y+2, -z; (vi) -x+2, -y+2, -z.
References
Brandenburg, K. & Putz, H. (2005). DIAMOND Crystal Impact GbR, Bonn, Germany.
Bruker (2004). SAINT-Plus and SADABS Bruker AXS Inc., Madison, Wisconsin. USA.
Bruker (2005). APEX2 Bruker AXS Inc., Madison, Wisconsin, USA.
Dyason, J. C., Engelhardt, L. M., Healy, P. C., Klich, H. L. & White, A. H. (1986). Aust. J. Chem.39, .
Farrugia, L. J. (1999). J. Appl. Cryst.32, 837–838.
Hanna, J. V., Boyd, S. E., Healy, P. C., Bowmaker, G. A., Skelton, B. W. & White, A. H. (2005). J. Chem. Soc. Dalton Trans. pp. .
Matthew, M., Palenik, G. J. & Carty, A. J. (1971). Can. J. Chem.49, .
Saravanabharathi, D., Monika, Venugopalan, P. & Samuelson, A. G. (2002). Polyhedron, 21, .
Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122.
Steyl, G. (2009). Acta Cryst. E65, m272.
[Figure ID: Fap1]
View of I (50% probability displacement ellipsoids). Phenyl rings are numbered Cxyz where x represents the phosphane to which the ring is attached, y represents the ring number and z the atom number in the ring. Only the first phenyl ring is completely numbered for illustrative purpose Hydrogen atoms have been omitted for clarity.
[Figure ID: Fap2]
Intermolecular C—H···F and intramolecular π–π interactions (dashed bonds) for I. Symmetry code (iii) -x + 1, -y + 1, -z + 1. Non-relavent hydrogen atoms and phenyl rings have been omitted for clarity.
[Figure ID: Fap3]
Intermolecular C—H···F (dashed bonds) for I. Symmetry codes (i) x - 1, y + 1, z, (iv) x, y - 1, z and (vi) -x + 2, -y + 2, -z. Non-relevant hydrogen atoms and phenyl rings have been omitted for clarity.
[Figure ID: Fap4]
Inter- and intramolecular C—H···O interactions (dashed bonds) for I. Symmetry code (iii) x - 1, y, z. Non-relevant hydrogen atoms and phenyl rings have been omitted for clarity.
[TableWrap ID: d1e307]
[Cu(NO3)(C18H12F3P)3]
Mr = 1074.29
F(000) = 1092
Triclinic, P1
Dx = 1.501 Mg m-3
Hall symbol: -P 1
Mo Kα radiation, λ = 0.71073 ?
a = 9.3861 (3) ?
Cell parameters from 9076 reflections
b = 12.2552 (4) ?
θ = 2.5–28.2°
c = 21.4820 (7) ?
u = 0.64 mm-1
α = 85.274 (2)°
β = 86.843 (1)°
Column, colourless
γ = 74.954 (1)°
0.38 × 0.11 × 0.08 mm
[TableWrap ID: d1e447]
Bruker X8 APEXII 4K KappaCCD diffractometer
11760 independent reflections
Radiation source: sealed tube
9439 reflections with I & 2σ(I)
Graphite monochromator
Rint = 0.030
Detector resolution: 512 pixels mm-1
θmax = 28.5°, θmin = 2.4°
φ and ω scans
h = -9→12
Absorption correction: multi-scan (SADABS; Bruker, 2004)
k = -16→16
Tmin = 0.792, Tmax = 0.950
l = -28→27
28458 measured reflections
[TableWrap ID: d1e570]
Refinement on F2
0 restraints
Least-squares matrix: full
H-atom parameters constrained
R[F2 & 2σ(F2)] = 0.035
w = 1/[σ2(Fo2) + (0.0333P)2 + 0.8637P] where P = (Fo2 + 2Fc2)/3
wR(F2) = 0.085
(Δ/σ)max = 0.001
Δρmax = 0.40 e ?-3
11760 reflections
Δρmin = -0.41 e ?-3
640 parameters
[TableWrap ID: d1e721]
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
[TableWrap ID: d1e741]
0.64094 (18)
1.01573 (14)
0.27195 (8)
0.0156 (3)
0.68685 (19)
1.07502 (15)
0.21964 (9)
0.0188 (4)
0.5860 (2)
1.15064 (16)
0.18194 (9)
0.0214 (4)
0.4384 (2)
1.16645 (16)
0.19755 (9)
0.0224 (4)
0.3879 (2)
1.11255 (17)
0.24917 (9)
0.0236 (4)
0.49013 (19)
1.03644 (16)
0.28659 (9)
0.0200 (4)
0.88511 (18)
0.99336 (15)
0.35054 (8)
0.0164 (4)
1.0241 (2)
0.93895 (17)
0.37273 (9)
0.0235 (4)
1.1054 (2)
0.99874 (18)
0.40190 (10)
0.0302 (5)
1.0452 (2)
1.11196 (18)
0.40800 (10)
0.0300 (5)
0.9084 (2)
1.16862 (18)
0.38719 (11)
0.0338 (5)
0.8282 (2)
1.10793 (16)
0.35806 (10)
0.0261 (4)
0.67292 (18)
0.86418 (15)
0.38106 (8)
0.0155 (3)
0.67507 (19)
0.89769 (15)
0.44123 (8)
0.0183 (4)
0.5868 (2)
0.86338 (16)
0.48895 (9)
0.0217 (4)
0.4963 (2)
0.79770 (16)
0.47510 (9)
0.0214 (4)
0.49013 (19)
0.76214 (15)
0.41629 (9)
0.0202 (4)
0.58129 (19)
0.79473 (15)
0.36951 (9)
0.0177 (4)
0.84201 (19)
0.55517 (15)
0.36385 (8)
0.0169 (4)
0.88652 (19)
0.60020 (16)
0.41492 (9)
0.0203 (4)
0.8305 (2)
0.58076 (18)
0.47462 (9)
0.0259 (4)
0.7292 (2)
0.51683 (18)
0.48172 (9)
0.0286 (5)
0.6808 (2)
0.47230 (17)
0.43309 (10)
0.0296 (5)
0.7382 (2)
0.49225 (16)
0.37315 (9)
0.0225 (4)
1.10916 (18)
0.48680 (15)
0.29250 (8)
0.0161 (4)
1.2149 (2)
0.49938 (16)
0.24626 (9)
0.0225 (4)
1.3602 (2)
0.43753 (17)
0.25149 (11)
0.0288 (5)
1.3979 (2)
0.36487 (17)
0.30303 (10)
0.0269 (4)
1.2974 (2)
0.34649 (18)
0.34868 (10)
0.0297 (5)
1.1516 (2)
0.40819 (17)
0.34301 (9)
0.0249 (4)
0.83035 (18)
0.52013 (15)
0.23431 (8)
0.0155 (3)
0.70057 (19)
0.58837 (16)
0.20949 (8)
0.0182 (4)
0.6262 (2)
0.55066 (17)
0.16533 (9)
0.0236 (4)
0.6842 (2)
0.44263 (18)
0.14708 (9)
0.0238 (4)
0.8096 (2)
0.37125 (17)
0.17122 (10)
0.0263 (4)
0.8839 (2)
0.41083 (16)
0.21519 (9)
0.0224 (4)
1.04880 (18)
0.69465 (14)
0.10744 (8)
0.0140 (3)
1.18958 (18)
0.70551 (15)
0.08908 (8)
0.0168 (4)
1.2899 (2)
0.62024 (16)
0.05907 (9)
0.0214 (4)
1.2481 (2)
0.52395 (16)
0.04881 (9)
0.0212 (4)
1.1117 (2)
0.50835 (16)
0.06709 (9)
0.0224 (4)
1.0117 (2)
0.59482 (15)
0.09661 (9)
0.0192 (4)
0.74569 (18)
0.81865 (14)
0.10980 (8)
0.0144 (3)
0.61174 (19)
0.85818 (15)
0.14206 (9)
0.0177 (4)
0.4793 (2)
0.88015 (16)
0.11152 (10)
0.0244 (4)
0.4848 (2)
0.86173 (16)
0.04930 (10)
0.0241 (4)
0.6133 (2)
0.82046 (17)
0.01569 (9)
0.0248 (4)
0.7452 (2)
0.79875 (16)
0.04667 (8)
0.0196 (4)
0.96604 (18)
0.93534 (14)
0.12332 (8)
0.0137 (3)
0.8948 (2)
1.00834 (15)
0.07499 (9)
0.0200 (4)
0.9262 (2)
1.11221 (16)
0.05949 (9)
0.0225 (4)
1.0311 (2)
1.13997 (15)
0.09233 (9)
0.0190 (4)
1.1049 (2)
1.07060 (16)
0.14004 (9)
0.0210 (4)
1.07114 (19)
0.96782 (15)
0.15582 (9)
0.0182 (4)
1.24915 (16)
0.72517 (14)
0.29043 (8)
0.0232 (4)
1.14700 (13)
0.76757 (11)
0.25203 (6)
0.0228 (3)
1.21663 (16)
0.68829 (12)
0.34380 (7)
0.0288 (3)
1.37844 (15)
0.71966 (15)
0.27340 (8)
0.0413 (4)
0.33854 (12)
1.23879 (10)
0.16002 (6)
0.0319 (3)
1.12332 (15)
1.17149 (11)
0.43652 (7)
0.0458 (4)
0.40845 (13)
0.76620 (10)
0.52191 (6)
0.0330 (3)
0.67367 (15)
0.49784 (12)
0.54008 (6)
0.0447 (4)
1.54253 (12)
0.30798 (11)
0.30944 (7)
0.0418 (3)
0.61304 (14)
0.40369 (11)
0.10379 (6)
0.0355 (3)
1.34503 (13)
0.44073 (10)
0.01912 (6)
0.0320 (3)
0.35528 (12)
0.88451 (11)
0.01908 (6)
0.0364 (3)
1.06177 (12)
1.24204 (9)
0.07802 (5)
0.0261 (3)
0.78177 (5)
0.90846 (4)
0.31532 (2)
0.01394 (9)
0.92541 (5)
0.58263 (4)
0.28780 (2)
0.01375 (9)
0.91661 (5)
0.80309 (4)
0.15007 (2)
0.01231 (9)
0.92130 (2)
0.01294 (6)
[TableWrap ID: d1e2072]
0.0158 (8)
0.0129 (9)
0.0179 (9)
-0.0022 (7)
-0.0035 (7)
-0.0036 (7)
0.0167 (8)
0.0160 (9)
0.0234 (10)
-0.0028 (7)
-0.0020 (7)
-0.0035 (7)
0.0265 (10)
0.0166 (9)
0.0217 (10)
-0.0066 (8)
-0.0040 (8)
0.0000 (7)
0.0231 (9)
0.0154 (9)
0.0281 (11)
-0.0017 (8)
-0.0144 (8)
0.0006 (8)
0.0145 (8)
0.0253 (11)
0.0304 (11)
-0.0027 (8)
-0.0071 (8)
-0.0021 (8)
0.0172 (8)
0.0226 (10)
0.0202 (10)
-0.0046 (8)
-0.0029 (7)
-0.0012 (7)
0.0139 (8)
0.0164 (9)
0.0190 (9)
-0.0034 (7)
-0.0020 (7)
-0.0020 (7)
0.0201 (9)
0.0185 (10)
0.0297 (11)
0.0007 (8)
-0.0072 (8)
-0.0029 (8)
0.0207 (9)
0.0300 (12)
0.0405 (13)
-0.0047 (9)
-0.0131 (9)
-0.0029 (9)
0.0306 (11)
0.0278 (11)
0.0375 (12)
-0.0154 (9)
-0.0142 (9)
-0.0013 (9)
0.0368 (12)
0.0165 (10)
0.0497 (14)
-0.0053 (9)
-0.0207 (10)
-0.0040 (9)
0.0228 (9)
0.0181 (10)
0.0370 (12)
-0.0013 (8)
-0.0143 (9)
-0.0036 (8)
0.0134 (8)
0.0139 (9)
0.0173 (9)
-0.0002 (7)
-0.0016 (7)
0.0001 (7)
0.0196 (9)
0.0149 (9)
0.0199 (9)
-0.0026 (7)
-0.0021 (7)
-0.0027 (7)
0.0258 (10)
0.0186 (10)
0.0177 (10)
0.0002 (8)
-0.0014 (7)
-0.0020 (7)
0.0200 (9)
0.0182 (10)
0.0231 (10)
-0.0021 (8)
0.0053 (7)
0.0026 (7)
0.0162 (8)
0.0158 (9)
0.0276 (10)
-0.0029 (7)
-0.0026 (7)
0.0012 (7)
0.0167 (8)
0.0150 (9)
0.0204 (9)
-0.0012 (7)
-0.0023 (7)
-0.0025 (7)
0.0161 (8)
0.0134 (9)
0.0179 (9)
0.0010 (7)
0.0020 (7)
0.0012 (7)
0.0165 (8)
0.0199 (10)
0.0211 (10)
0.0007 (7)
-0.0007 (7)
0.0019 (7)
0.0228 (9)
0.0292 (11)
0.0185 (10)
0.0056 (8)
-0.0010 (8)
0.0001 (8)
0.0302 (11)
0.0268 (11)
0.0197 (10)
0.0042 (9)
0.0103 (8)
0.0067 (8)
0.0323 (11)
0.0214 (11)
0.0338 (12)
-0.0083 (9)
0.0142 (9)
0.0013 (9)
0.0258 (10)
0.0150 (9)
0.0253 (10)
-0.0041 (8)
0.0049 (8)
-0.0005 (8)
0.0153 (8)
0.0129 (9)
0.0197 (9)
-0.0024 (7)
-0.0007 (7)
-0.0022 (7)
0.0188 (9)
0.0181 (10)
0.0278 (11)
-0.0018 (8)
0.0018 (8)
0.0034 (8)
0.0175 (9)
0.0226 (11)
0.0441 (13)
-0.0038 (8)
0.0080 (9)
-0.0001 (9)
0.0145 (9)
0.0202 (10)
0.0429 (13)
0.0040 (8)
-0.0076 (8)
-0.0083 (9)
0.0301 (11)
0.0255 (11)
0.0249 (11)
0.0083 (9)
-0.0057 (9)
0.0002 (8)
0.0248 (10)
0.0229 (11)
0.0212 (10)
0.0030 (8)
0.0021 (8)
0.0011 (8)
0.0146 (8)
0.0160 (9)
0.0162 (9)
-0.0052 (7)
0.0026 (7)
-0.0002 (7)
0.0187 (8)
0.0163 (9)
0.0204 (9)
-0.0068 (7)
0.0009 (7)
0.0014 (7)
0.0231 (9)
0.0255 (11)
0.0241 (10)
-0.0110 (8)
-0.0043 (8)
0.0044 (8)
0.0273 (10)
0.0337 (12)
0.0169 (10)
-0.0189 (9)
-0.0003 (8)
-0.0031 (8)
0.0235 (9)
0.0238 (11)
0.0344 (12)
-0.0089 (8)
0.0054 (8)
-0.0143 (9)
0.0167 (9)
0.0191 (10)
0.0305 (11)
-0.0021 (7)
0.0020 (8)
-0.0073 (8)
0.0144 (8)
0.0148 (9)
0.0121 (8)
-0.0030 (7)
-0.0020 (6)
0.0013 (6)
0.0154 (8)
0.0153 (9)
0.0196 (9)
-0.0040 (7)
-0.0021 (7)
0.0003 (7)
0.0146 (8)
0.0218 (10)
0.0266 (10)
-0.0028 (7)
0.0005 (7)
-0.0012 (8)
0.0225 (9)
0.0176 (10)
0.0202 (10)
0.0013 (8)
0.0009 (7)
-0.0039 (7)
0.0290 (10)
0.0154 (9)
0.0242 (10)
-0.0087 (8)
0.0022 (8)
-0.0028 (7)
0.0199 (9)
0.0174 (9)
0.0214 (10)
-0.0077 (7)
0.0023 (7)
-0.0005 (7)
0.0147 (8)
0.0135 (8)
0.0164 (9)
-0.0067 (7)
-0.0028 (6)
0.0019 (7)
0.0167 (8)
0.0159 (9)
0.0213 (10)
-0.0052 (7)
-0.0024 (7)
-0.0015 (7)
0.0131 (8)
0.0223 (10)
0.0379 (12)
-0.0049 (8)
-0.0032 (8)
-0.0008 (8)
0.0190 (9)
0.0205 (10)
0.0358 (12)
-0.0108 (8)
-0.0165 (8)
0.0094 (8)
0.0312 (10)
0.0270 (11)
0.0207 (10)
-0.0155 (9)
-0.0107 (8)
0.0048 (8)
0.0200 (9)
0.0232 (10)
0.0177 (9)
-0.0098 (8)
-0.0030 (7)
0.0020 (7)
0.0133 (8)
0.0128 (8)
0.0152 (9)
-0.0039 (7)
0.0030 (6)
-0.0024 (6)
0.0233 (9)
0.0187 (10)
0.0199 (10)
-0.0087 (8)
-0.0051 (7)
0.0013 (7)
0.0300 (10)
0.0178 (10)
0.0191 (10)
-0.0063 (8)
-0.0041 (8)
0.0051 (7)
0.0224 (9)
0.0125 (9)
0.0225 (10)
-0.0066 (7)
0.0099 (7)
-0.0033 (7)
0.0178 (9)
0.0188 (10)
0.0290 (11)
-0.0086 (8)
-0.0003 (7)
-0.0044 (8)
0.0155 (8)
0.0170 (9)
0.0226 (10)
-0.0049 (7)
-0.0034 (7)
0.0003 (7)
0.0156 (7)
0.0231 (9)
0.0315 (10)
-0.0032 (7)
-0.0046 (7)
-0.0089 (7)
0.0144 (6)
0.0267 (7)
0.0269 (7)
-0.0059 (6)
-0.0067 (5)
0.0062 (6)
0.0338 (8)
0.0245 (8)
0.0250 (8)
-0.0007 (6)
-0.0099 (6)
0.0000 (6)
0.0131 (7)
0.0582 (11)
0.0545 (11)
-0.0075 (7)
-0.0034 (7)
-0.0180 (9)
0.0277 (6)
0.0272 (7)
0.0392 (7)
-0.0039 (5)
-0.0192 (5)
0.0091 (5)
0.0462 (8)
0.0346 (8)
0.0653 (10)
-0.0196 (6)
-0.0318 (7)
-0.0038 (7)
0.0361 (7)
0.0334 (7)
0.0298 (7)
-0.0134 (6)
0.0123 (5)
0.0017 (5)
0.0517 (8)
0.0537 (9)
0.0229 (7)
-0.0095 (7)
0.0156 (6)
0.0076 (6)
0.0165 (6)
0.0341 (8)
0.0685 (10)
0.0086 (5)
-0.0121 (6)
-0.0083 (7)
0.0444 (7)
0.0440 (8)
0.0280 (7)
-0.0263 (6)
-0.0070 (6)
-0.0078 (6)
0.0287 (6)
0.0238 (6)
0.0409 (7)
-0.0006 (5)
0.0087 (5)
-0.0140 (5)
0.0242 (6)
0.0418 (8)
0.0470 (8)
-0.0159 (6)
-0.0236 (5)
0.0143 (6)
0.0366 (6)
0.0156 (6)
0.0289 (6)
-0.0135 (5)
0.0089 (5)
-0.0020 (5)
0.0130 (2)
0.0125 (2)
0.0160 (2)
-0.00207 (17)
-0.00181 (16)
-0.00245 (17)
0.0129 (2)
0.0121 (2)
0.0153 (2)
-0.00204 (17)
-0.00006 (16)
0.00020 (17)
0.01112 (19)
0.0127 (2)
0.0135 (2)
-0.00410 (17)
-0.00106 (16)
0.00032 (16)
0.01211 (10)
0.01249 (11)
0.01381 (11)
-0.00253 (8)
-0.00091 (8)
-0.00025 (8)
[TableWrap ID: d1e3484]
C111—C116
C225—H225
C111—C112
C226—H226
1.8372 (18)
C231—C236
C112—C113
C231—C232
C112—H112
1.8209 (18)
C113—C114
C232—C233
C113—H113
C232—H232
C233—C234
C114—C115
C233—H233
C115—C116
C115—H115
C234—C235
C116—H116
C235—C236
C121—C126
C235—H235
C121—C122
C236—H236
1.8249 (17)
C311—C312
C122—C123
C311—C316
C122—H122
1.8340 (18)
C123—C124
C312—C313
C123—H123
C312—H312
C313—C314
C124—C125
C313—H313
C125—C126
C125—H125
C314—C315
C126—H126
C315—C316
C131—C132
C315—H315
C131—C136
C316—H316
1.8263 (18)
C321—C322
C132—C133
C321—C326
C132—H132
1.8236 (17)
C133—C134
C322—C323
C133—H133
C322—H322
C323—C324
C134—C135
C323—H323
C135—C136
C135—H135
C324—C325
C136—H136
C325—C326
C211—C216
C325—H325
C211—C212
C326—H326
1.8166 (18)
C331—C332
C212—C213
C331—C336
C212—H212
1.8385 (17)
C213—C214
C332—C333
C213—H213
C332—H332
C333—C334
C214—C215
C333—H333
C215—C216
1.3624 (19)
C215—H215
C334—C335
C216—H216
C335—C336
C221—C226
C335—H335
C221—C222
C336—H336
1.8199 (18)
C222—C223
C222—H222
1.2757 (19)
C223—C224
2.1182 (12)
C223—H223
2.2901 (5)
2.2840 (5)
C224—C225
2.3256 (5)
C225—C226
C116—C111—C112
118.43 (16)
C231—C232—H232
C116—C111—P1
123.28 (14)
C234—C233—C232
117.67 (18)
C112—C111—P1
118.20 (13)
C234—C233—H233
C113—C112—C111
121.34 (17)
C232—C233—H233
C113—C112—H112
F23—C234—C235
118.14 (18)
C111—C112—H112
F23—C234—C233
118.74 (18)
C114—C113—C112
118.08 (18)
C235—C234—C233
123.11 (17)
C114—C113—H113
C234—C235—C236
118.50 (18)
C112—C113—H113
C234—C235—H235
F11—C114—C115
118.73 (17)
C236—C235—H235
F11—C114—C113
118.43 (17)
C231—C236—C235
120.30 (18)
C115—C114—C113
122.83 (17)
C231—C236—H236
C114—C115—C116
118.59 (17)
C235—C236—H236
C114—C115—H115
C312—C311—C316
118.70 (16)
C116—C115—H115
C312—C311—P3
121.87 (13)
C115—C116—C111
120.70 (18)
C316—C311—P3
119.29 (13)
C115—C116—H116
C313—C312—C311
120.86 (16)
C111—C116—H116
C313—C312—H312
C126—C121—C122
119.30 (16)
C311—C312—H312
C126—C121—P1
122.57 (13)
C314—C313—C312
118.43 (16)
C122—C121—P1
118.08 (14)
C314—C313—H313
C123—C122—C121
120.47 (18)
C312—C313—H313
C123—C122—H122
F31—C314—C313
118.77 (16)
C121—C122—H122
F31—C314—C315
118.34 (17)
C124—C123—C122
118.28 (18)
C313—C314—C315
122.88 (17)
C124—C123—H123
C314—C315—C316
118.14 (17)
C122—C123—H123
C314—C315—H315
F12—C124—C123
118.94 (18)
C316—C315—H315
F12—C124—C125
117.93 (19)
C315—C316—C311
120.98 (16)
C123—C124—C125
123.13 (18)
C315—C316—H316
C124—C125—C126
118.07 (19)
C311—C316—H316
C124—C125—H125
C322—C321—C326
119.14 (16)
C126—C125—H125
C322—C321—P3
118.73 (13)
C121—C126—C125
120.75 (18)
C326—C321—P3
122.01 (13)
C121—C126—H126
C323—C322—C321
120.44 (17)
C125—C126—H126
C323—C322—H322
C132—C131—C136
118.98 (16)
C321—C322—H322
C132—C131—P1
123.15 (13)
C324—C323—C322
118.23 (17)
C136—C131—P1
117.86 (13)
C324—C323—H323
C133—C132—C131
120.39 (16)
C322—C323—H323
C133—C132—H132
F32—C324—C323
118.35 (18)
C131—C132—H132
F32—C324—C325
117.95 (18)
C134—C133—C132
118.55 (17)
C323—C324—C325
123.70 (17)
C134—C133—H133
C324—C325—C326
117.62 (18)
C132—C133—H133
C324—C325—H325
F13—C134—C133
118.11 (17)
C326—C325—H325
F13—C134—C135
118.56 (16)
C325—C326—C321
120.84 (17)
C133—C134—C135
123.33 (17)
C325—C326—H326
C134—C135—C136
117.47 (16)
C321—C326—H326
C134—C135—H135
C332—C331—C336
118.71 (16)
C136—C135—H135
C332—C331—P3
122.55 (13)
C135—C136—C131
121.24 (17)
C336—C331—P3
118.56 (13)
C135—C136—H136
C333—C332—C331
121.02 (16)
C131—C136—H136
C333—C332—H332
C216—C211—C212
119.37 (17)
C331—C332—H332
C216—C211—P2
123.31 (14)
C334—C333—C332
118.15 (17)
C212—C211—P2
117.31 (13)
C334—C333—H333
C213—C212—C211
120.73 (18)
C332—C333—H333
C213—C212—H212
F33—C334—C333
118.72 (17)
C211—C212—H212
F33—C334—C335
118.29 (16)
C214—C213—C212
117.87 (19)
C333—C334—C335
122.97 (17)
C214—C213—H213
C334—C335—C336
118.45 (17)
C212—C213—H213
C334—C335—H335
F21—C214—C215
118.41 (19)
C336—C335—H335
F21—C214—C213
C335—C336—C331
120.68 (17)
C215—C214—C213
123.51 (18)
C335—C336—H336
C214—C215—C216
118.15 (19)
C331—C336—H336
C214—C215—H215
O3—N1—O2
121.54 (17)
C216—C215—H215
O3—N1—O1
118.99 (17)
C211—C216—C215
120.35 (19)
O2—N1—O1
119.45 (15)
C211—C216—H216
N1—O1—Cu1
129.87 (11)
C215—C216—H216
C121—P1—C131
103.52 (8)
C226—C221—C222
118.76 (17)
C121—P1—C111
102.89 (8)
C226—C221—P2
122.63 (14)
C131—P1—C111
101.99 (8)
C222—C221—P2
118.38 (14)
C121—P1—Cu1
115.18 (6)
C223—C222—C221
120.54 (18)
C131—P1—Cu1
116.00 (6)
C223—C222—H222
C111—P1—Cu1
115.38 (6)
C221—C222—H222
C211—P2—C221
102.44 (8)
C224—C223—C222
118.67 (18)
C211—P2—C231
103.80 (8)
C224—C223—H223
C221—P2—C231
104.60 (8)
C222—C223—H223
C211—P2—Cu1
117.00 (6)
F22—C224—C223
118.50 (18)
C221—P2—Cu1
114.73 (6)
F22—C224—C225
118.46 (19)
C231—P2—Cu1
112.79 (6)
C223—C224—C225
123.04 (18)
C321—P3—C311
102.69 (8)
C224—C225—C226
118.02 (19)
C321—P3—C331
101.81 (8)
C224—C225—H225
C311—P3—C331
103.93 (8)
C226—C225—H225
C321—P3—Cu1
119.88 (6)
C225—C226—C221
120.88 (18)
C311—P3—Cu1
113.47 (6)
C225—C226—H226
C331—P3—Cu1
113.18 (6)
C221—C226—H226
O1—Cu1—P2
103.96 (4)
C236—C231—C232
118.97 (16)
O1—Cu1—P1
112.11 (4)
C236—C231—P2
123.58 (14)
P2—Cu1—P1
119.537 (18)
C232—C231—P2
117.38 (13)
O1—Cu1—P3
C233—C232—C231
121.42 (18)
P2—Cu1—P3
112.289 (18)
C233—C232—H232
P1—Cu1—P3
115.765 (18)
C116—C111—C112—C113
C332—C331—C336—C335
P1—C111—C112—C113
174.93 (14)
P3—C331—C336—C335
-175.65 (14)
C111—C112—C113—C114
O3—N1—O1—Cu1
168.52 (13)
C112—C113—C114—F11
-178.64 (16)
O2—N1—O1—Cu1
C112—C113—C114—C115
C126—C121—P1—C131
-86.16 (17)
F11—C114—C115—C116
178.39 (16)
C122—C121—P1—C131
91.29 (16)
C113—C114—C115—C116
C126—C121—P1—C111
19.76 (18)
C114—C115—C116—C111
C122—C121—P1—C111
-162.80 (15)
C112—C111—C116—C115
C126—C121—P1—Cu1
146.16 (15)
P1—C111—C116—C115
-175.00 (14)
C122—C121—P1—Cu1
-36.39 (17)
C126—C121—C122—C123
C132—C131—P1—C121
P1—C121—C122—C123
-177.78 (16)
C136—C131—P1—C121
-178.98 (14)
C121—C122—C123—C124
C132—C131—P1—C111
-104.43 (15)
C122—C123—C124—F12
179.89 (19)
C136—C131—P1—C111
74.42 (15)
C122—C123—C124—C125
C132—C131—P1—Cu1
129.34 (14)
F12—C124—C125—C126
-179.9 (2)
C136—C131—P1—Cu1
-51.81 (15)
C123—C124—C125—C126
C116—C111—P1—C121
-115.02 (15)
C122—C121—C126—C125
C112—C111—P1—C121
68.61 (15)
P1—C121—C126—C125
177.63 (17)
C116—C111—P1—C131
-7.93 (17)
C124—C125—C126—C121
C112—C111—P1—C131
175.70 (14)
C136—C131—C132—C133
C116—C111—P1—Cu1
118.70 (14)
P1—C131—C132—C133
178.38 (14)
C112—C111—P1—Cu1
-57.67 (15)
C131—C132—C133—C134
C216—C211—P2—C221
-104.51 (16)
C132—C133—C134—F13
-178.86 (16)
C212—C211—P2—C221
75.32 (15)
C132—C133—C134—C135
C216—C211—P2—C231
F13—C134—C135—C136
-179.62 (16)
C212—C211—P2—C231
-176.01 (14)
C133—C134—C135—C136
C216—C211—P2—Cu1
129.11 (14)
C134—C135—C136—C131
C212—C211—P2—Cu1
-51.06 (15)
C132—C131—C136—C135
C226—C221—P2—C211
P1—C131—C136—C135
-176.86 (14)
C222—C221—P2—C211
-168.41 (14)
C216—C211—C212—C213
C226—C221—P2—C231
-102.03 (16)
P2—C211—C212—C213
-178.51 (14)
C222—C221—P2—C231
83.53 (15)
C211—C212—C213—C214
C226—C221—P2—Cu1
133.86 (14)
C212—C213—C214—F21
-179.82 (17)
C222—C221—P2—Cu1
-40.58 (16)
C212—C213—C214—C215
C236—C231—P2—C211
-94.43 (16)
F21—C214—C215—C216
179.91 (17)
C232—C231—P2—C211
88.54 (14)
C213—C214—C215—C216
C236—C231—P2—C221
12.62 (17)
C212—C211—C216—C215
C232—C231—P2—C221
-164.42 (13)
P2—C211—C216—C215
178.61 (15)
C236—C231—P2—Cu1
137.95 (14)
C214—C215—C216—C211
C232—C231—P2—Cu1
-39.08 (15)
C226—C221—C222—C223
C322—C321—P3—C311
155.05 (14)
P2—C221—C222—C223
172.58 (15)
C326—C321—P3—C311
-28.92 (16)
C221—C222—C223—C224
C322—C321—P3—C331
-97.54 (14)
C222—C223—C224—F22
-176.99 (17)
C326—C321—P3—C331
78.49 (16)
C222—C223—C224—C225
C322—C321—P3—Cu1
28.18 (16)
F22—C224—C225—C226
177.41 (18)
C326—C321—P3—Cu1
-155.80 (12)
C223—C224—C225—C226
C312—C311—P3—C321
135.09 (15)
C224—C225—C226—C221
C316—C311—P3—C321
-49.29 (16)
C222—C221—C226—C225
C312—C311—P3—C331
29.31 (16)
P2—C221—C226—C225
-171.92 (16)
C316—C311—P3—C331
-155.07 (14)
C236—C231—C232—C233
C312—C311—P3—Cu1
-94.04 (14)
P2—C231—C232—C233
175.64 (14)
C316—C311—P3—Cu1
81.58 (15)
C231—C232—C233—C234
C332—C331—P3—C321
-10.69 (17)
C232—C233—C234—F23
179.96 (16)
C336—C331—P3—C321
164.33 (14)
C232—C233—C234—C235
C332—C331—P3—C311
95.75 (16)
F23—C234—C235—C236
179.45 (17)
C336—C331—P3—C311
-89.23 (15)
C233—C234—C235—C236
C332—C331—P3—Cu1
-140.71 (14)
C232—C231—C236—C235
C336—C331—P3—Cu1
34.31 (15)
P2—C231—C236—C235
-176.07 (15)
N1—O1—Cu1—P2
-47.17 (15)
C234—C235—C236—C231
N1—O1—Cu1—P1
83.31 (15)
C316—C311—C312—C313
N1—O1—Cu1—P3
-159.63 (15)
P3—C311—C312—C313
177.38 (14)
C211—P2—Cu1—O1
115.58 (8)
C311—C312—C313—C314
C221—P2—Cu1—O1
C312—C313—C314—F31
179.49 (16)
C231—P2—Cu1—O1
-124.11 (7)
C312—C313—C314—C315
C211—P2—Cu1—P1
-10.33 (7)
F31—C314—C315—C316
-178.93 (17)
C221—P2—Cu1—P1
-130.38 (6)
C313—C314—C315—C316
C231—P2—Cu1—P1
109.98 (6)
C314—C315—C316—C311
C211—P2—Cu1—P3
-150.88 (7)
C312—C311—C316—C315
C221—P2—Cu1—P3
P3—C311—C316—C315
-176.91 (14)
C231—P2—Cu1—P3
-30.58 (6)
C326—C321—C322—C323
C121—P1—Cu1—O1
P3—C321—C322—C323
174.63 (14)
C131—P1—Cu1—O1
-124.75 (7)
C321—C322—C323—C324
C111—P1—Cu1—O1
116.10 (7)
C322—C323—C324—F32
-179.21 (16)
C121—P1—Cu1—P2
118.34 (7)
C322—C323—C324—C325
C131—P1—Cu1—P2
F32—C324—C325—C326
179.20 (16)
C111—P1—Cu1—P2
-121.93 (6)
C323—C324—C325—C326
C121—P1—Cu1—P3
-102.42 (7)
C324—C325—C326—C321
C131—P1—Cu1—P3
136.47 (6)
C322—C321—C326—C325
C111—P1—Cu1—P3
P3—C321—C326—C325
-174.51 (14)
C321—P3—Cu1—O1
-179.52 (8)
C336—C331—C332—C333
C311—P3—Cu1—O1
P3—C331—C332—C333
174.43 (14)
C331—P3—Cu1—O1
-59.34 (7)
C331—C332—C333—C334
C321—P3—Cu1—P2
C332—C333—C334—F33
-179.35 (16)
C311—P3—Cu1—P2
-45.46 (6)
C332—C333—C334—C335
C331—P3—Cu1—P2
-163.59 (6)
F33—C334—C335—C336
178.36 (15)
C321—P3—Cu1—P1
-65.89 (7)
C333—C334—C335—C336
C311—P3—Cu1—P1
172.40 (6)
C334—C335—C336—C331
C331—P3—Cu1—P1
[TableWrap ID: d1e5879]
D—H···A
D—H···A
C122—H122···O2
C336—H336···O1
C126—H126···F22i
C136—H136···O3ii
C215—H215···F13iii
C315—H315···F33iv
C332—H332···F32v
C326—H326···F33vi
Article Categories:Metal-Organic Papers
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